Long ride almost always on the weekend. I'm sure it's pretty difficult for many to cut out for 3-5 hours during the work week. Long run during the week is certainly more doable, 2 hours or so. I like the concept of separating them by a few days. Up to this point I've always done the long Sat/Sun workout thing, but scheduling my long run mid-week might be a better training option, if I can figure out a way to squeeze it in :)

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"The first virtue in a soldier is endurance of fatigue; courage is only the second virtue."
- Napoleon Bonaparte