I read that a couple days ago. this comment from the author was pretty cool:
"Had in interesting conversation with a former mentor and scuba dive master about the oxygen environment in the block 1 CM for ground testing. He asked about oxygen toxicity at 16.7psia, and the question brought me up short. My immediate response was "Oh, well, they were wearing their suits, so it doesn't matter what the cabin was pressurized at........oh." Because pressure suits need to be pressurized to work. And the block 1 CM didn't have a multigas system, as Eric mentioned, so that means their suits were pressurized with pure O2 at a level even higher than the 16.7psia of the CM.
So, I asked Apollo EECOM Sy Liebergot about it, since he's pretty friendly with Ars (EECOMs were the flight controllers responsible for watching over the spacecraft's environmental systems, among other things). He also didn't know and made some inquiries, and then he told me the crew's suits would have been at about 17 psia, just a whisker over ambient pressure in the cabin.
So what about toxicity?
In what can only be called a marvelous example of a laconic reply, Sy drawled, "I've been told it takes a while."
One more example of how NASA's culture of risk avoidance differs now versus back then. "
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LLLEEEEEEEEEEEERRRROOOYYY JEEENNNNNKKKIIINNNNNS!!!