There are lots. These are direct mount, from memory. There are surely more that I'm not thinking of:
Some Willier models (NDR even has both disc and direct mounts, on one bike)
Pinarello Dogma/Gan and maybe Prince
Cannondale Supersix
Specialized SL6, if you can still find one
Trek Emonda

Factor O2V2 or O2 VAM have direct mount rim brake options

Thanks so much for the info. I'll look into those options. You're right about the SL6. Saw an S-works on ebay and missed it, but it was also $3,900.

Colnago frames still do direct mount frame brakes. At this stage I will go a Colnago V3RS when my Cannondale rim brake frame dies or I want to change things up. Italian frame, Italian groupset a match made in heaven...

Chapter2 out of New Zealand. $3019 for a rim brake frameset.
https://www.chapter2bikes.com/range/rere